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August 24, 2017

Exposed Copper Risk

Exposed Copper Risk
We received many PCB's where a modification have been completed. The modification involved soldering a chip cap to an existing pad and adjacent surface ground layer. The modification is correct, but no coating have been applied to the stripped area.

This PCB is used in an outside environment exposed to high humidity and temperatures extremes. Should we be concerned with corrosion? What should we do?

A.H.

Experts Comments

I would not recommend leaving exposed copper in ANY environment.  There are a couple of ways to deal with this issue:
  • Since this appears to be a very small area, I would recommend using a soldermask touch up pen to cover just that area.
  • A conformal coating would also work but would probably have to be applied with a small brush to the exposed copper.
  • That area could be sprayed with an aerosol conformal coat.  This will eliminate the exposed copper, but is much more difficult to control and you may cover areas where you do not want it.
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Mark Finstad
Senior Applications Engineer
Flexible Circuit Technologies
Mark Finstad has over 30 years in the flex circuit industry in both design and manufacturing. He is a regular speaker at IPC APEX (Professional development courses) and PCB West (flex circuit design courses). He is also vice chair of IPC-2223 and active member of IPC-6013. Finstad has extensive experience with both domestic and off-shore manufacturing.
The copper will be more susceptible to oxidization, but will likely not cause too much more of a risk for corrosion. However, coating it epoxy or masking is easy, cheap and will rule out any corrosion or other issues.
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T.J. Hughes
Manufacturing Engineer
Esterline Interface Technologies
Mr. Hughes has been in the electronics manufacturing field for 20 years. Operating the processes and as a manufacturing engineer for the last 14 years. He is also a CIT as well as an SMTA Certified Process Engineer.
I would suggest you purchase some solder mask touch up pens and simply touch in the areas of exposed Copper. This should be more than sufficient. If you cannot purchase these then a light coat on the area of conformal coating will be sufficient, but get one with a UV light trace so you can double check it is covered.
Greg York
Technical Sales Manager
BLT Circuit Services Ltd
Greg York has twenty two years of service in Electronics industry. York has installed over 350 Lead Free Lines in Europe with Solder and flux systems as well as Technical Support on SMT lines and trouble shooting.
The exposure copper adjacent the surface ground layer has the potential for corrosion from ionic contamination and environmental effects. Halide ions, notably chloride and bromide ions can penetrate areas of the copper surface. When the copper pad is exposed to environmental effects, tiny pits can form on the copper surface.

The oxidation of the copper enables pitting and crevice corrosion.  To mitigate these corrosion potentials, I recommend that the exposed copper be cleaned post soldering and then coated to prevent environmental exposure. 
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Mike Bixenman
CTO
Kyzen Corp.
Mr. Bixenman is the CTO for Kyzen Corp. Kyzen Corp. is a leading provider of engineered cleaning fluids for high technology manufacturing environments.
 The exposed copper is definitely a problem for outdoor environment and humidity. The copper is likely to corrode and eaten away due to corrosion. The corrosion product (salt) produced could form acid with excess moisture and lower insulation resistance, between tracks nearby.

One type of correction can be applying conformal coating (Polyurethane- preferred) selectively to exposed area that can provide some protection from corrosion. Exposed copper definitely does not meet IPC-A-610E requirements.
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KN Murli
Head-Quality
Astra Microwave Products, Hyderabad, AP India
Holds Degree in Engineering, started off as Scientist/Engineer in ISRO (Indian Space Research Organization) in Quality Assurance of Space hardware Electronics Production. Worked in the area of Parts, Material and Process; DPA, FA and Process Qualification for space and ground hardware. Later moved into Private sector and worked in the area of Quality Management Systems & ISO 9001 certification. Currently hold a position as Head-Quality in RF/Microwave Product manufacturing for Defense and Aerospace segment.
Absolutely.. Bare copper? Ever leave a penny outside? Green in no time.. Either go with conformal coating for the entire board, my suggestion, or localized conformal coating for the reworked area..

You indicate that the PCB is used  "in an outside environment exposed to high humidity and temperatures extremes. Should we be concerned with corrosion? " If your product is currently not protected from these harsh environmental conditions are you not already seeing failures? A PCB used in those condition should be completed encased in a quality conformal coating.
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Jerry Karp
President
JSK Associates
Based in. Northern California since 1971. Founded JSK Associates in 1979. Actively involved in soldering, cleaning, chemistries. 30 years experience in EOS/ESD control.
Yes you should be concerned if you expect your product to be in the filed longer than 18 months, and if your product is exposed to humidity and temperatures.

You would need to confirm that all off you pre manufacturing process such as wave soldering and hand soldering are RoHS compliant. Non RoHS compliant products such as fluxes,  contain acids such as  chlorine or bromine. This is corrosive after the soldering operation and would cause corrosion of the surface during operation of the product.

  Many cleaning and testing methods were developed to clean the surfaces and to test to insure the surfaces were noncorrosive afterwards. The majority of these test methods involved checking for ionic contamination after the cleaning was performed. A passing product would have a low level of ionic contamination.(I strongly recommend that you do this test, to confirm that the products used on your PCB are RoHS compliant.)

RoHS compliant products, such as "no-clean" fluxes compose of organic acids such as adipic acid or citric acids. These organic acids are decomposed by the temperatures reached during soldering, and are likely to have very slow or low corrosive effects.  

I recommend that you make use of a solder mask pen, which will offer a solder mask coating over your exposed copper. This is the safest, and most cost effective way to resolve your problem.
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Kishan Sarjoo
Process Engineering Manager - Electronics
Altech UEC, South Africa
Currently with Altech UEC and responsible for technology road map in PCBA electronic manufacturing and technical support for PCBA electronic manufacturing for Altech UEC and its JDM's. Over 7 years in SMT, Radial Insertion, Wave solder & Test Applications.
Yes!
Mahendra Gandhi
SME - PWB Technologies
Northrop Grumman
Mahendra Gandhi has been working in interconnect industry since 1972.
In a word, yes, you should be concerned. The level of risk really depends on the enclosure and operating environment. If the product will continually produce enough heat to keep it above dew point, the risk will be substantially lower. If the product does not operate continuously, however, then the risk is higher.

Another issue is the levels of ionic materials in the end use environment. If, for instance, the product might be used where salt is present, e.g. near the ocean, the corrosion risk is greater. The exposed copper will always represent a greater corrosion risk than the solder, however there is a corrosion risk for both. Conformal coating can help to protect against moderate amounts of moisture. It will not protect against gross amounts of liquid, however.
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Fritz Byle
Process Engineer
Astronautics
Fritz's career in electronics manufacturing has included diverse engineering roles including PWB fabrication, thick film print & fire, SMT and wave/selective solder process engineering, and electronics materials development and marketing. Fritz's educational background is in mechanical engineering with an emphasis on materials science. Design of Experiments (DoE) techniques have been an area of independent study. Fritz has published over a dozen papers at various industry conferences.
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