Ask the Experts
INDEX
ASK
PANEL
JOIN
COMMENT
April 27, 2020

Hand Sanitizer Contamination

Due to the COVID-19, the plant is wanting to use a sanitizer called Sani-Cide 94 which is a quaternary ammonium sanitizer. It is going to be placed on tables with sprays and other surfaces around the plant.

Can any of the possible particles that fly to the air affect the Printed Circuit Boards?

H.H.

Expert Panel Responses

Yes. We are collecting data on many of the decontamination systems and will be publishing the soon. We have ion chromatography and sir testing.

image
Terry Munson
President/Senior Technical Consultant
Foresite
Mr. Munson, President and Founder of Foresite, has extensive electronics industry experience applying Ion Chromatography analytical techniques to a wide spectrum of manufacturing applications.

The short answer is yes, there is risk. The main active ingredient, dimethyl benzyl ammonium chloride, Is an ammonium salt and does contain chlorine.

Chlorine compounds, in combination with atmospheric moisture, can contribute to reduced insulation resistance and failures due to dendritic growth.

image
Fritz Byle
Process Engineer
Astronautics
Fritz's career in electronics manufacturing has included diverse engineering roles including PWB fabrication, thick film print & fire, SMT and wave/selective solder process engineering, and electronics materials development and marketing. Fritz's educational background is in mechanical engineering with an emphasis on materials science. Design of Experiments (DoE) techniques have been an area of independent study. Fritz has published over a dozen papers at various industry conferences.

Quaternary ammonium compounds are usually made as halide salts (e.g. chloride salts). Particles that land on circuit boards will deposit these salts which are conductive and potentially corrosive. With the right conditions of quaternary ammonium salt, plus moisture, plus voltage, then electrochemical migration or corrosion could occur.

I suggest keeping the circuit boards at least 6 feet away from the spray of sanitizer, to try and avoid contact.

image
Tony Lentz
Field Applications
FCT Assembly
Tony has worked in the electronics industry since 1994. He worked as a process engineer at a circuit board manufacturer for 5 years. Since 1999, Tony has worked for FCT Companies as a laboratory manager, facility manager, and most recently a field application engineer. He has extensive experience doing research and development, quality control, and technical service with products used to manufacture and assemble printed circuit boards. He holds B.S. and M.B.S. degrees in Chemistry.

Not sure on this one, would need to conduct a DOE to determine. However, I have advised to use caution on using non-approved cleaners on ESD treated surfaces.

It is possible and likely to destroy the dissipative properties of the item being cleaned.

image
Tod Cummins
Director of Corporate Quality Assurance
Delta Group Electronics Inc.
Tod has been working in the Aerospace Electronics Industry for 25 years, beginning with 4+ years working for PCB fabricator ending as the Quality Manager and 20 years with Delta Group Electronics Inc. an AS9100 registered electronics contract manufacture. Currently position is Director of Corporate Quality Assurance.

The material warnings saying "prolonged soaking may cause damage to metal instruments" and "follow pesticide disposal instructions" would give me pause.

Metals like ENIG finishes and relatively soft solder could possibly be damaged if it will damage metal instruments. If this has to be used, assemblies, pwbs, and materials should be removed from the area until everything is dried.

image
Kevin Mobley
PCBA Engineering Liaison
General Atomics Electromagnetic Systems Group
Kevin has over 30 years of experience in process and manufacturing engineering serving in both EMS and OEM companies. Expertise includes all aspects of SMT as well as wave solder and CCA materials such as PCBs, solder material, and component finishes. Kevin has developed processes for thousands of assemblies from stencil printing to conformal coating and testing.

According to Sani-Cide 94 SDS, the material will react with oxidizers, strong acids and reactive metals. Tin, lead and copper are considered to be reactive metals but I do not believe that flying particles will affect your boards, however, direct contact will.

Keep all PCB's from coming into direct contact with the sanitizer.

image
Edithel Marietti
Senior Manufacturing Engineer
Northrop Grumman
Edithel is a chemical engineer with 20 year experience in manufacturing & process development for electronic contract manufacturers in US as well as some major OEM's. Involved in SMT, Reflow, Wave and other assembly operations entailing conformal coating and robotics.

Ten years ago, Doug Pauls and Michael Vosatka of Rockwell Collins, authored a paper for IPC APEX that provided a detailed examination of some typical hand sanitizers and hand lotions and their impact on high-reliability electronic hardware.

Their research, which included SIR (Surface Insulation Resistance), FTIR and, ion chromatography, is very timely again in today's environment. A link to the full white paper can be found at the end of the brief:
See the link that follows, it will take you to the Tech Brief. https://tinyurl.com/yafynpro

image
Charlie Pitarys
Technical Expert Sales Support
Kyzen Corporation
Charlie Pitarys has over thirty years of industry experience and has been with KYZEN for twenty-one years. Charlie is a former Marine and a retired Sargent First Class in the Army Reserves. His previous employers include Hollis and Electrovert. Charlie continues to use his expertise on cleaning processes and machine mechanics to help KYZEN customers and partners improve their cleaning operations.

Quaternary ammonium compounds (QACs) are antimicrobial disinfectants commonly found in cleaning solutions used in residential, commercial, medical settings, restaurants and food production facilities.

While there appears to be no published guidelines for using QACs on printed circuit boards, caution should be considered since certain laboratory tests have indicated prolonged use of some types of QAC disinfectants were detected to have impaired the reproductive health of mice.

We further recommend contacting the manufacturer of Sani-Cide 94 for more details and clarification.

image
Carlos Bouras
General Manager
Nordson SELECT
Carlos Bouras is the General Manager of Nordson SELECT and has over 30 years of experience in the electronics manufacturing industry. Carlos's expertise is in process engineering, product development and manufacturing operations. For the past 15 years Carlos has focused specifically on automated assembly issues and is the holder of several US patents for non-contact dispensing and precision dispensing of adhesives for the packaging of microprocessor devices.

IMO not a good idea. The ammonium , per SE, is a urea product. Urea contains calcium. Calcium is a salt, Salts are corrosive to metallic surfaces, Therefore....IPA 90e% to 10 % DI water is a far better disinfectant for hard surfaces. CDC uses this as a guideline.

I try to keep my responses short and to point. Flowery responses provide the same results except at a slower rate. Alcohol has been a universal disinfectant for years upon years. The addition of DI water slows the evaporation rate and increases the time factor for virus destruction. Adding an ammonium factor IMO cannot help the situation, but in fact may create a problem.

image
Jerry Karp
President
JSK Associates
Based in. Northern California since 1971. Founded JSK Associates in 1979. Actively involved in soldering, cleaning, chemistries. 30 years experience in EOS/ESD control.
Submit A Comment

Comments are reviewed prior to posting. You must include your full name to have your comments posted. We will not post your email address.

Your Name


Your Company
Your E-mail


Your Country
Your Comments



Free Newsletter Subscription
Circuitnet is built for professionals who bear the responsibility of looking ahead, imagining the future, and preparing for it.

Insert Your Email Address