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April 25, 2018

What Is This Contamination?

These images are from a failed position-sensor in our power plant. It is potted with some kind of epoxy-compound because of vibration-issues.

We don't think the potting is done by the manufacturer, it is more likely done later in the assembly-line because it's done only for us.

What Is This Contamination?
What Is This Contamination?


What do you think? What are we seeing here?

This sensor failed after only 2-3 years of operation among with several others.

M.K.

Experts Comments

Need to know the surface finish on the PWB.
Gerard O'Brien
President
S T and S Testing and Analysis
Gerald O'Brien is Chairman of ANSI J-STD 003, and Co Chairman of IPC 4-14 Surface Finish Plating Committee. He is a key member of ANSI J-STD 002 and 311 G Committees Expert in Surface finish, Solderability issues and Failure analysis in the PWA, PWB and component fields.
Looking at the images gives me several ideas as to what happened:
  1. The wash process before coating was not able to remove all solder flux residues thus corroding those areas.
  2. The original coating thickness was below minimum acceptance criteria in those areas allowing some oxidation to develop.
  3. There were either pin holes or bubbles that allowed moisture to get in.
  4. The assembly was reworked after the coating was done and was not properly cleaned and/or re-coated.
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Edithel Marietti
Senior Manufacturing Engineer
Northrop Grumman
Edithel is a chemical engineer with 20 year experience in manufacturing & process development for electronic contract manufacturers in US as well as some major OEM's. Involved in SMT, Reflow, Wave and other assembly operations entailing conformal coating and robotics.

There is almost definitely corrosion going on, so the question is what is the source? From what we can see, it is limited to certain terminals, so my working hypothesis would be assembly soils that were not removed and later created an ionic path between terminals where a voltage gradient exists. The ionic path and moisture permeating the potting compound then combined with the voltage difference to drive corrosion of the terminals.

This theory plays well with your hypothesis that the potting is being done at a post-assembly step. If the potting is done at a different location/organization than the assembly, they may not understand what soils are present, e.g. flux residues, and may not be taking the proper steps to ensure reliability.

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Fritz Byle
Process Engineer
Astronautics
Fritz's career in electronics manufacturing has included diverse engineering roles including PWB fabrication, thick film print & fire, SMT and wave/selective solder process engineering, and electronics materials development and marketing. Fritz's educational background is in mechanical engineering with an emphasis on materials science. Design of Experiments (DoE) techniques have been an area of independent study. Fritz has published over a dozen papers at various industry conferences.

From the picture, it is difficult to be sure.

I would suggest there is a corrosive contaminant under the epoxy coating, likely left-over residue from a so called "no clean" flux.

Before the Epoxy coating is applied, the assembly must be cleaned no matter what type of solder flux used. Such corrosion can also be caused by other contamination left behind by the assembly process, even finger prints.
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Paul Austen
Senior Project Engineer
Electronic Controls Design Inc
Paul been with Electronic Controls Design Inc. (ECD) in Milwaukie, Oregon for over 34 years as a Senior Project Engineer. He has seen and worked with the electronic manufacturing industry from many points of view, including: technician, designer, manufacture, and customer. His focus has been the design and application of thermal process measurement tools used to improve manufacturing processes like: mass reflow and wave soldering, bread baking, paint and powder curing, metal heat treatment and more.
The pictures are difficult to zoom into but it appears there is corrosion occurring. Is there a no clean flux on these circuit boards? If so that could be a potential source for corrosion, especially when the device is in operation. Potting material does not necessarily stop corrosion or electro migration from occurring. It likely slows the process enabling the device to operate over a longer period of time before failure.
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Tony Lentz
Field Applications
FCT Assembly
Tony has worked in the electronics industry since 1994. He worked as a process engineer at a circuit board manufacturer for 5 years. Since 1999, Tony has worked for FCT Companies as a laboratory manager, facility manager, and most recently a field application engineer. He has extensive experience doing research and development, quality control, and technical service with products used to manufacture and assemble printed circuit boards. He holds B.S. and M.B.S. degrees in Chemistry.

The images from a failed position-sensor used in your power plant, appear to be potted or staked with some kind of epoxy-compound because of end application vibration-issues. You don't think the potting is done by the manufacturer, it is more likely done later in the assembly-line because it's done only for you. This sensor failed after only 2-3 years of operation. How long do known good assemblies last for comparison?

Typically, when I encounter contamination of circuit card assemblies I recommend comparing a known good verses bad and extracting several samples for different locations to submit for FTIR, SEM/EDX, and IC analysis testing. The FTIR in my humble opinion will be the fastest and the cheapest for organics ( e.g., residual flux, adhesives , or coatings chemistry) that may result in subsequent contamination or corrosion failures. The SEM/EDX allows me to determine the inorganics involved ( e.g., Metals) that do not contain carbon. They have high melting points and particular high or low electrical conductivity properties. Inorganic substances are used in many applications and in various fields.. Often, they are used as coatings, catalysts, medicines, pigments and fuels. Finally, I would submit the known good verses bad circuit card assemblies for IC testing to identify Ionics per IPC-TM-650-2.3.28. IC testing will reveal anions and cations involved and specific levels critical to board assembly cleanliness. When certain levels are exceeded and exposed to moisture , bias, and temperatures subsequent contamination or corrosion failures result. After doing this analysis you will be able to determine if the failure is a result of supplier issues( e.g., Flux, adhesive, coating), Manufacturing(e.g., process problem) , Design ( e.g., pitch issues) , or end application ( e.g., harsh environment ).

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Mark Northrup
VP of Advanced Technical Operations
IEC Electronics
Mark has over 25 years' experience in electronics fabrication, quality and reliability while working for IEC Electronics, GE, Motorola, ORS, etc. He has most recently established IEC Electronics Analysis and Testing Laboratories (IATL), LLC in Albuquerque, NM for electronics and material analysis testing in the military, medical, and industrial industries. His area of expertise includes PCB, PCBA, components, analytical and electrical analysis techniques.
Very difficult to determine the cause from the pictures provided, however there appears to be a conformal coat or potting present on the board. From the bubbles between the leads on the IC it looks to be the original application. I am guessing you are seeing 1 of 2 items, either poor rework was performed prior to conformal coat during the manufacturing process or there is a net in board getting hot. I would need to look at this under a scope to really determine what is going on. I am leaning toward rework during the manufacturing process and flux was not removed prior to potting.
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Tod Cummins
Director of Corporate Quality Assurance
Delta Group Electronics Inc.
Tod has been working in the Aerospace Electronics Industry for 20+ years, beginning with 4 years working for PCB fabricator ending as the Quality Manager and 16 years with Delta Group Electronics Inc. an AS9100 registered electronics contract manufacture. Currently position is Director of Corporate Quality Assurance.
Without further investigation, I can only guess this board suffered a short. Most likely from an insufficient cleaning process and possibly dendrite growth. It is very possible flux residue was left behind which may past initial testing but fail later in the field.
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Brien Bush
Manufacturing Applications Specialist
Cirtronics Corp.
Mr. Bush has 20 years experience in electronics contract manufacturing. Major areas of expertise include through hole, SMT, wave and selective soldering.

This looks like some form of corrosion. Most likely this was cause by flux residues beneath the coating.

Any applied coating to prevent environmental conditions from affecting the product are not impervious to the absorption of moisture. Hence, if the unit has been in the field for two years, then the operating environment may be the source of the mechanism for the corrosion on the product.

My recommendations would be to have the material analyzed to determine the exact material composition, which can then be evaluated as to its source and control of such.
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Leo Lambert
Vice President, Technical Director
EPTAC Corporation
At EPTAC Corporation, Mr. Lambert oversees content of course offerings, IPC Certification programs and provides customers with expert consultation in electronics manufacturing, including RoHS/WEEE and lead free issues. Leo is also the IPC General Chairman for the Assembly/Joining Process Committee.
Looks likely you have some corrosive residue left in the via and leaching out, causing the corrosion and subsequent failure. Is this on the power part of the PCB? I would suspect something pretty active (Hydrochloric/Hydrobromic Acid) especially if the finish of the PCB is HASL and it won't matter if its coated or not it will still corrode and sometimes faster with the coating on.
Greg York
Technical Sales Manager
BLT Circuit Services Ltd
Greg York has twenty two years of service in Electronics industry. York has installed over 350 Lead Free Lines in Europe with Solder and flux systems as well as Technical Support on SMT lines and trouble shooting.
In looking at the photos below, I would suspect that the contamination is actually corrosion. We see this quite frequently.
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Renee Michalkiewicz
General Manager
Trace Laboratories
Renee has been with Trace and an IPC member for 16 years. She has managed all military and commercial PB qualification and conformance testing and training, as well as product qualification and testing in the areas of solder pastes, fluxes, solder masks, and conformal coat. She is the chairman of the IPC Testing and the IPC-J-STD-004 Flux Specification Committees and the Vice Chairman of the Assembly and Joining Committee. She has published more than a dozen papers and presented at numerous electronics conferences.
With not a lot of data here are few things that I can think about - this can be some sort of oxidation caused by contamination in the assembly process:
  • Oxidation on parts and/or boards
  • Incorrect oven profile and/or inefficient cleaning and drying process that can cause inactivated flux residue to be left over on the board or just moisture left on the board and then trapped under the coating layer
  • For no clean processes (even not highly recommended in conjunction with coating) flux crystals can cause oxidation issues if the coating material brakes the outer layer in a chemical reaction
  • Another thing that can cause this is the bare board manufacturing process - contamination can be trapped in between layers, via holes, etc. and with time field failures are to be expected
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Georgian Simion
Engineering and Operations Management
Independent Consultant
Georgian Simion is an independent consultant with 20+ years in electronics manufacturing engineering and operations.
Contact me at georgiansimion@yahoo.com.
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