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February 10, 2012
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November 9, 2009

Hot or Cold DI Water Rinse

How important is the use of hot water in our deionized batch and inline cleaning systems? As I understand it, a hot water rinse will lower the surface tension to better clean under low profile parts.

Could we get equally good results using a room temperature rinse within our DI systems?

R. S.

Experts Comments

You can get decent results but not equally good results. The rinse will be more active and do a better job in a shorter period of time. The old rule of thumb, double the activity for every 10 degree C rise in Temp applies here.

You have to find your own sweet spot however. Perhaps some SIR testing at different temps is in order if you really want to find that sweet spot for your operation.

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Daniel (Baer) Feinberg
Vice President
Fein-Line Associates
Mr. Feinberg is a forty-four year industry veteran and a former President of Morton Electronic Materials (Dynachem). Feinberg presently owns Fein-Line Associates, a management consulting and market research company.

Surface tension of water can be reduced and its solvency can be increased by increasing its temperature. Hot rinse water has better capability of creeping underneath components and rinsing off potentially re-deposited contaminants faster from the wash cycle.

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Umut Tosun
Application Technology Manager
Zestron America
Mr. Tosun has published numerous technical articles. As an active member of the SMTA and IPC organizations, Mr. Tosun has presented a variety of papers and studies on topics such as "Lead-Free Cleaning" and "Climatic Reliability".

I would strongly recommend heated DI water as some wetting agents used in fluxes will Gel if hit with cold water instead of heated. Also heating the water will aid drying times considerably. Recommend 45-50C water.

I'm not too sure about heating water to make it more searching for low standoff components but adding a small amount of Saponifier/cleaning agent will help with this considerably and neutralise any activators present.

Greg York
Technical Sales Manager
BLT Circuit Services Ltd
Greg York has twenty two years of service in Electronics industry. York has installed over 350 Lead Free Lines in Europe with Solder and flux systems as well as Technical Support on SMT lines and trouble shooting.

The answer is "It depends"...

Hot water will dissolve residues more quickly than cold water. In a time-critical process step, hot water will be more efficient from a through-put standpoint.

Also, materials will typically be more soluble in hot water than in cold. So, cleaner and faster with hot water, in general..And, yes, hot water will have a lower surface tension.

Jim Williams
Chairman
Polyonics, Inc.
Jim Willimas is a PhD Chemist in Polymers and Materials Science. He specialize in printing, cleaning, inks, and coatings used in electronics manufacturng operations. Williams has more than 30 years experience.

In nearly every circumstance, hot water (120-150F) will be better than room temperature water (70-80F) in terms of removing residues from soldering processes. While the surface tension concern that you mention is one aspect in this equation, the fact that solubility of most organic materials is better in hotter water is another strong case for going with hotter water.

The greater solubility of organic materials in hotter water generally means that you will have better luck removing residues in hot water than room temperature water.

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Brian Smith
General Manager - Electronic Assembly Americas
DEK
Mr. Smith has been supporting customers in the electronics assembly industry since 1994. His expertise is focused on solder paste printing and reducing soldering defects. He holds a BS in Chemical Engineering and an MBA in Marketing. He has authored several papers in trade magazines and at industry conferences. He is an SMTA Certified Process Engineer.
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