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May 15, 2006

Is it possible to run Pb-Free reflow without nitrogen?

Is it possible to run Pb-Free reflow without nitrogen? We know that nitrogen will improve the solderability of our assemblies, but nitrogen does adds significant cost.

L.G.S.

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Ask the Experts Comments

May 24, 2006

The quick answer is DEFINITELY!

The Japanese have been running Lead Free without nitrogen since 1999 with great success. Virtually all Camcorders, Cameras, DVD Players, TV's, Computers, Audio Equipment, etc made in Japan are made without nitrogen and WITH Lead Free Paste.

There is a great article in the May issue of Circuits Assembly Magazine that goes into some detail on this subject. And Eli Westerlaken deserves all the credit so I will just forward the link:

http://circuitsassembly.com/cms/content/view/3262/95/

You will need to work with your paste vendor to find a suitable formulation but as you noted that tends to be much less expensive than running nitrogen!

Marc Peo, President
Heller Industries Inc.
mpeo@hellerindustries.com

Marc PeoMr. Peo has been with Heller Industries for over 20 years and has been President for the past 8 years. Marc has authored several industry articles on Soldering, Flux collection, nitrogen use and Lead Free conversion and has served on the SMEMA Dual Rail committee, the APIA Consortium, the JARA Association and SMEMA Steering Committee.

May 18, 2006

It is possible, but it could also be cost effective to use nitrogen. Depending upon your resources and time, it might be valuable to run an experimental design where you look at rework/scrap rate with and without nitrogen. Depending upon the cost of your product and first pass yields, the reduction in scrap might pay for the cost of the nitrogen.

Dr. Craig D. Hillman, CEO & Managing Partner
DfR Solutions
chillman@dfrsolutions.com

Dr. Craig D. HillmanDr. Hillman's specialties include best practices in Design for Reliability, strategies for transitioning to Pb-free, supplier qualification (commodity and engineered products), passive component technology and printed board failure mechanisms. Dr. Hillman has over 30 publications and has presented on a wide variety of reliability issues to over 150 companies and organizations.

May 18, 2006

In a one word answer YES.

We have many customers operating lead free processes without Nitrogen.
However we have other customers running lead free processes with Nitrogen.
The Nitrogen discussion continues.

There are certainly benefits to Nitrogen atmosphere in a reflow oven, however your lead free solder paste, components, board material, board finish, and other factors will determine what if any benefit Nitrogen will have for your operation.

In our work we have seen a dramatic improvement on the solderability of lead free solder pastes over the last six years.

The first lead free solder pastes we printed and reflowed six years ago barely moved from their printed shape and position. We have all seen the pictures of lead free solder paste that remained in its printed location after reflow soldering. They certainly reflowed but almost did not spread at all.
The newer lead free solder pastes we have printed and reflowed spread much better. Still not the same spreading capability as tin lead material but much better then the older lead free solder paste products.

As always, work with your materials and component suppliers to identify the correct reflow environment and reflow profile for your operation.

Joe Belmonte, Project Manager Adv Process Dev
Speedline Technologies
jbelmonte@speedlinetech.com

Joe BelmonteMr. Belmonte has been a process engineer and process engineering manager in the electronic manufacturing industry for over 28 years. Joe is currently a Project Manger at Speedline Technologies Advanced Process Group. Joe's primary responsibilities include managing advanced process development projects such as Lead Free Process Development, and miniature component assembly. Joe has written papers for at numerous industry trade shows and professional society meetings.

May 18, 2006

It is certainly possible to manufacture and reflow surface mount assemblies using Pb-free soldering materials without using nitrogen. As long as we are talking about SAC alloys using Type III or Type IV powder in the paste. Advances in solder paste technology have produced materials that are Pb-free air-reflow compatible that produce no-clean residues that are clear, colorless, and pin testable.

Once the powder sizes go below Type IV and/or with some exotic alloys the use of nitrogen may be required in order to produce reliable, well wetted components. Where we do see a need to implement nitrogen is in the wave soldering process. The use of nitrogen reduces the amount of dross, reduces the chance of bridging and other defects.

Dr. Brian Toleno, Application Engineering
Henkel Technologies
brian.toleno@us.henkel.com

Dr. Brian TolenoDr. Brian Toleno is the Application Engineering Team leader for Henkel Technologies. He is responsible for the technical service and application engineering for Henkel's electronics assembly materials, including solder paste, underfills, PCB protection materials, and underfills. He holds a Ph.D. in Analytical Chemistry from The Pennsylvania State University and a B.S. degree in Chemistry from Ursinus College.

May 18, 2006

If using a selective soldering process, nitrogen is critical for the reasons you mention but also to prevent nozzles from clogging. There are many study's available showing the benefits of nitrogen and the money that you actually save when using it. You save a lot of waste because much less dross is created compared to not using it, and more importantly you save on re-work because of the better flow characteristics. While using nitrogen it is also possible to lower the already high temperature of the Pb-free solder pot, which also helps to eliminate delamination and contamination.

So, you can see with the initial investment of nitrogen, in the long run it can save you money and headaches.

Todd O'Neil, Product Mgr, Selective Solder
JUKI Automation Sys.
toneil@jas-smt.com

Todd O'NeilMr. O'Neil has been part of the electronics manufacturing field for nearly 17 years. As Product Manager for Selective Soldering at JUKI, his main objective is to continue the "Lowest Cost of Ownership", and superb reputaion for sales and serivice that JUKI has been so well know for with their Pick and Place equipment.







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