The advise offered starts with the assumption that the Rework system used is operating properly and capable of Lead-Free processing. That temperature measurements are credible and thermocouples used are properly attached with high temperature thermally conductive adhesive to the sample. That the solder paste supplier's recommended profile, component and substrate manufacturers' thermal limitations are under consideration.

If so, then to minimize the thermal impact of the Rework process starts with a preheat cycle from ambient then ramping with a gentle heating rate of about 1 degree per second to attain an overall assembly temperature of no less than 150C. The more uniform the temperature distribution is across the assembly during preheating, the lower the chance that damage will occur due to dissimilar thermal expansion and contraction.

The type of heat applied can dramatically impact thermal uniformity across the assembly. Very focused heat applied to the bottom of a Rework site alone may "burn the pads off" in an attempt to elevate the Rework site temperatures above the melting point of the alloy, i.e SAC305 at 221C. This is especially so with heavy mass boards that require significant more energy than nominal size boards with a thickness of 0.062". Once properly preheated, similar Reflow and Cooling ramps should be observed while minimizing the site's overall time above liquidous (TAL) to about 60 seconds or less and overall peak temperature (Tmax) to typically less than 240C. Controlled cooling should continue at similar rates to ensure proper solder interconnect formation and to prevent component and board warpage.

The key to a job like this one is Pre-Heat.

A board of this thickness will just heat sink away any input from an Iron or Rework station unless the entire product is at elevated temperature. 

Frankly, I am not an expert on Rework so I will let the Rework gurus give you the best approach. But we have seen customers run large product through the Reflow oven to get it up to temperature and then move it to the rework station to remove and replace parts.

Don’t get the wrong idea. I am not saying that anyone should buy a reflow oven for the purposes of preheating for re-work. The example was to show an extreme case and demonstrate that the entire assembly needs to be up to an elevated temperature to perform the task.

Most rework stations will have a preheat option and that is where the real action is.

At the end of the day it is all about data. So pull in the Rework vendors, give them a sample board and let them have at it. Most will come running. And those who don’t are staying away because they can’t help you!

Most companies use either hot air / solder tip with a vacuum or a solder fountain. The concern is rarely with burning pads and more with copper dissolution. The general experience has been you have approximately 30 seconds of exposure before you dissolve all the copper from the bond pad.

I suggest you contact AirVac Engineering on this.

Multip pin connectors can be a bear to remove. I'm sure we would use a solder fountain to tackle such a job. We have a few detailed procedures and articles on our website you may want to look over. See the following.

Guide
7.2.2 Soldering Through Hole Components, Solder Fountain Method

Feature Articles
A Time Saver, But Beware - How to Use a Solder Fountain
Multi-Pin Connector Removal and Replacement: Tackling "Goliath"